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N-Methyl-m-toluidine N,3-dimethylaniline CAS 696-44-6 secondary aromatic amine intermediate for dyes and tolnaftate C8H11N

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CAS NO.: 696-44-6
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N-Methyl-M-Methylaniline

N-Methyl-m-toluidine (also known as N,3-dimethylaniline or 3-(methylamino)toluene, CAS 696-44-6, EC 211-795-0) is a secondary aromatic amine and a versatile intermediate for dyes and pharmaceuticals. Royalchem supplies it at ≥99% purity (water ≤0.2%) as a colourless to pale-yellow liquid with a molecular weight of 121.18 and a density of about 0.957 g/cm³.
Product Description

N-Methyl-m-toluidine (N,3-Dimethylaniline)

High-Purity Secondary Aromatic Amine — Dye & Pharmaceutical Intermediate
CAS: 696-44-6         EC: 211-795-0         Assay: ≥ 99.0%

N-Methyl-m-toluidine (N,3-dimethylaniline, CAS 696-44-6) is a secondary aromatic amine and a versatile intermediate for dyes and pharmaceuticals. It combines an aniline ring bearing a meta-methyl group with an N-methyl substituent, giving a reactive secondary-amine site for coupling, acylation, and alkylation. Royalchem Spain supplies it at ≥ 99% purity as a colourless to pale-yellow liquid, delivered from our Valladolid distribution hub by drum or IBC.

Technical Specifications (COA Data)
Assay (GC) ≥ 99.0%
Appearance Colourless to pale-yellow liquid
Water Content (KF) ≤ 0.2%
Molecular Weight 121.18 g/mol
Density (25 °C) ≈ 0.957 g/cm³
Boiling Point ≈ 205 °C
Flash Point ≈ 90 °C
*Regulatory: EINECS-listed (EC 211-795-0); REACH pre-registered; manufactured under ISO 9001. Like other aromatic toluidines it is toxic and harmful by inhalation, skin contact, and ingestion (risk of methaemoglobinaemia) and may harm aquatic life — handle only with full PPE and effective ventilation. Typically classified as a toxic substance (Class 6.1) for bulk transport. Always refer to the current SDS for the authoritative CLP classification and shipping details.
Chemical Structure
N-Methyl-m-toluidine N,3-dimethylaniline CAS 696-44-6 chemical structure C8H11N
Key Properties
• Molecular Formula: C₈H₁₁N
           • Molecular Weight: 121.18
           • Boiling Point: ≈ 205 °C
           • Density (25 °C): ≈ 0.957 g/cm³

Main Applications

Dye & Pigment Intermediates

Coupling component and building block for azo dyes and organic pigments; its meta-methyl and N-methyl groups help tune shade, brightness, and substantivity on the finished colourant.

Pharmaceutical Intermediates

N-methyl-m-tolyl building block in the synthesis of active ingredients — most notably the antifungal tolnaftate, for which it serves as the characteristic amine moiety and reference impurity.

Specialty & Organic Synthesis

Secondary aromatic amine reagent for custom synthesis, agrochemical and rubber-chemical intermediates, and a methylated toluidine building block for N-acylation and N-alkylation chemistry.

Logistics & Packaging

Standard Packaging:

200 kg HDPE or steel drums, or IBC totes (approx. 1000 kg). Distributed by Royalchem Spain from our Valladolid hub. Shelf life 24 months in original sealed packaging.

Storage Conditions:

Store in tightly sealed containers in a cool, dry, dark, well-ventilated area, away from heat, ignition sources, oxidising agents, and acids; nitrogen blanketing is recommended, as this aromatic amine darkens on exposure to air and light. Toxic — handle with respiratory protection and full PPE.


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Address:
Valladolid, Spain
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